1 1.天津大学 环境科学与工程学院, 天津300072
2 2.国网山东省电力公司电力科学研究院, 济南250002
3 3.天津大学 化工学院, 天津300072
4 4.天津大学 海洋科学与技术学院, 天津 300072
重金属污染具有高毒性、持久存留和生物积累等特性, 严重危害人体健康和生态安全。本研究通过氯化钙对玉米芯残渣和膨润土混合物进行碱改性, 在无氧条件下高温煅烧制备了一种碱改性生物炭-膨润土复合物(CaO-Bent-CB)。该复合物的比表面积高, 达到441.1 m2/g, 明显高于直接煅烧制备的生物碳(132.7 m2/g)和碱改性生物炭(177.2 m2/g)。进一步评价了该复合物对水中铅离子吸附性能, 结果表明在水中铅离子浓度为120 mg/L, 膨润土与玉米芯残渣质量比为1:5, 用量为1 g/L条件下, 吸附6 h后铅离子去除率达98%, 吸附量为109.6 mg/g, 均高于生物炭(13.4 mg/g)、膨润土(72.9 mg/g)和碱改性生物炭(86.9 mg/g)。此外, 采用CaO-Bent-CB对铅离子污染土壤进行稳定化处理, 当土壤中铅离子浓度为2200 mg/kg, CaO-Bent-CB用量为土壤干重的8%时, 在pH=3.2的硫酸-硝酸浸提液中浸出12 h, 酸浸出铅离子浓度低至4.5 mg/L, 低于危险废物鉴别标准值(5 mg/L)。上述研究结果表明这种生物炭-膨润土共改性复合物在重金属污染水体和土壤修复中具有很好的应用前景。
玉米芯残渣 生物炭 粘土 重金属 土壤修复 corncob residue biochar clay heavy metal soil remediation
Author Affiliations
Abstract
1 State Key Laboratory of Chemical Engineering, Tianjin Key Laboratory of Membrane Science and Desalination Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
We present a facile and effective method for fabrication of the localized surface plasmon resonance (LSPR) optical fiber sensor assisted by two polydopamine (PDA) layers with enhanced plasmonic sensing performance. The first PDA layer was self-polymerized onto the bare optical fiber to provide the catechol groups for the reduction from Ag+ to Ago through chelating and redox activity. As the reduction of Ag+ proceeds, Ag nanoparticles (NPs) were grown in-situ on the PDA layer with uniform distribution. The second PDA layer was applied to prevent Ag NPs from oxidating and achieve an improvement of LSPR signal. The PDA/Ag/PDA-based optical fiber sensor has an enhanced LSPR sensitivity of 961 nm/RIU and excellent oxidation resistance. The stable PDA/Ag/PDA-based LSPR sensor with high optical performance is very promising for future application in optical sensing field.
LSPR optical fiber polydopamine in-situ growth silver nanoparticles Photonic Sensors
2020, 10(2): 97
